Material Safety Data Sheet

For Coatings, Resins and Related Materials

NOTE:   CHEMTREC, CANUTEC and National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals

24 Hour Emergency:  1-800-123-4567 CHEMTREC:  1-800-424-9300

National Response in Canada  CANUTEC:  613-996-6666

Outside U.S. and Canada  Chemtrec:   202-483-7616

 

Section 1 - Chemical Product / Company Information

 

Product Name:

INT. POLYURETH. GLOSS AEROSOL

Revision Date:

04/08/2009

Identification Number:

24X01

Print Date:

8-16-2010

Product Use/Class:

POLYURETHANE

 

 

Manufacturer:

Deft, Inc.  (CAGE CODE 33461)
17451 Von Karman Ave
Irvine, Ca.  92614

Information Phone:

Emergency Phone:

(949) 474-0400

(800) 424-9300

Section 2 - Hazards Identification

*** Emergency Overview ***:  Extremely Flammable! Amber liquid in aerosol container. Harmful by inhalation, in contact with skin, and if swallowed. May cause burns to the skin. Contact with eyes or skin causes irritation. Affects the central nervous system.

Effects Of Overexposure - Eye Contact:   Exposure to liquid, aerosol, or vapors may cause irritation, tearing, redness, and swelling accompanied by a stinging sensation. Direct eye contact may cause irritation. Exposure may cause conjunctivitis. Damage may occur to the cornea or lens of the eye.

Effects Of Overexposure - Skin Contact:   Direct skin contact may cause irritation. Symptoms may include swelling, redness, and rash. Prolonged or repeated skin contact may cause dermatitis, drying, and defatting due to the solvent properties. Exposure may cause skin burns. It is possible for a component to pass through the skin into the body, but is unlikely to cause harmful effects when handled and used safely.

Effects Of Overexposure - Inhalation:   Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes) & acute nervous system depression characterized by the following progressive steps: headache, dizziness, staggering gait, confusion, unconsciousness, or coma. Exposure may cause pulmonary edema. Exposure may cause coughing. Inhalation of vapors may cause feelings of euphoria and anesthetic effects. Prolonged exposure may cause narcosis, rapid breathing and death from asphyxiation. Inhalation may cause headaches, difficult breathing, and loss of consciousness. Respiratory depression, failure, or death may result from overexposure. Exposure to high concentrations or overexposure to one or more components may cause respiratory depression or failure, difficult breathing, chest constriction, loss of consciousness, or death.

Effects Of Overexposure - Ingestion:   Ingestion may cause gastrointestinal irritation, abdominal pain, nausea, vomiting, and diarrhea. May result in possible corrosive action in the mouth, stomach tissue, and digestive tract. Vomiting may cause aspiration of the solvent, resulting in chemical pneumonitis. Harmful or fatal if swallowed. Ingestion causes damage to the central nervous system. It may include, acute nervous system depression, which is characterized by the following progressive steps: headache, dizziness, staggering gait, confusion, drowsiness, unconsciousness, or coma. Ingestion may cause a burning sensation in the mouth and esophagus. Lung inflammation or other lung injury may occur if methyl n-propyl ketone enters the lungs through vomiting or swallowing.

Effects Of Overexposure - Chronic Hazards:  Prolonged contact will cause drying and cracking of the skin, due to defatting action. Skin sensitization, asthma, or other allergic responses may develop. Contains components listed as a Carcinogen: NTP? : No, IARC Monographs? : Yes, OSHA Regulated? : No. Symptoms of overexposure may occur for up to 48 hours after the original exposure occurred. WARNING: This product contains a chemical known to the state of California to cause cancer. The neurotoxic effects caused by other chemicals may be worsened or the time of onset may be shortened by a component. In addition, kidney and liver damage caused by other chemicals may be worsened or the time of onset may be shortened by a component. A component has been shown to cause kidney damage in male rats. The kidney effects are not expected to effect humans. Overexposure to a component has been shown to cause damage to the liver, kidneys, and testis in laboratory animals. A component(s) has been shown to cause blood abnormalities, lower activity of certain immune system cells, effects the hearing, mild reversible liver effects, central nervous damage, and cataracts in laboratory animals. Ethylbenzene, a component of this formulation, has been shown to cause harm to the fetus in labortory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain. Methyl n-propyl ketone, a component of this formulation, has been shown to cause harm to the fetus in labortory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain.

Primary Route(s) Of Entry:  Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact

Section 3 - Composition / Information On Ingredients

Component CAS Number Weight % Reporting Ranges
ACETONE 67-64-1 10-30
ISOBUTANE (2-METHYLPROPANE) 75-28-5 10-30
STODDARD SOLVENT (REFINED PETROLEUM DISTILLATE) 8052-41-3 10-30
PROPANE 74-98-6 7-13
METHYL n-PROPYL KETONE 107-87-9 7-13
SOLVENT NAPHTHA, LIGHT ALIPHATIC 64742-89-8 5-10
AROMATIC HYDROCARBON 64742-95-6 1-5
PAINT DRIER 22464-99-9 0.1-1.0
ETHYL BENZENE 100-41-4 0.1-1.0

 

ALL INGREDIENTS ARE ON THE TSCA INVENTORY LIST, UNLESS OTHERWISE NOTED IN SECTION 8.

 

Section 4 - First Aid Measures

First Aid - Eye Contact:  If material gets into eyes, flush with water immediately for 20 minutes. Hold eyelids open to rinse out the entire eye. Consult a physician. If symptoms develop (irritation) from airborne exposure, move to fresh air.

First Aid - Skin Contact:  Remove contaminated clothing and shoes. In case of contact, immediately flush skin with plenty of water and wash affected areas thoroughly with soap and water. Wash contaminated clothing thoroughly before reuse or discard. If rash or other symptoms develop (irritation), consult a physician.

First Aid - Inhalation:  Move to fresh air in case of accidental inhalation of vapors. Give oxygen or artificial respiration if needed. Asthmatic type symptoms may develop and maybe immediate or delayed by several hours. In the case of inhalation of aerosol/mist, call 911 immediately.

First Aid - Ingestion:  Do not induce vomiting. Do not give anything to an unconscious person. Obtain medical help.

Section 5 - Fire Fighting Measures

 

Flash Point (°F): < 20 TCC

LOWER EXPLOSIVE LIMIT (%): 0.9

UPPER EXPLOSIVE LIMIT (%): 12.

Extinguishing Media: Alcohol Foam, Carbon Dioxide, Dry Chemical, Foam, Water Fog, Water Spray, Dry Sand

Unusual Fire And Explosion Hazards: Keep containers tightly closed. Isolate from heat, sparks, electrical equipment and open flame. Fire or intense heat may cause violent rupture of packages. Application to hot surfaces requires special precautions. Toxic gases may form when product burns. Remove all sources of ignition. Vapors and fumes may form an ignitable/explosive mixture with air. Vapors are heavier than air and may flow along surfaces, may travel/spread along the floors/ground, or can be moved by ventilation to a distant ignition source and flashback. Do not use a cutting or welding torch near or on a drum of product, because vapors may ignite explosively, even if the drum is empty and contains only product residue. Fire may ensue when product comes in contact with strong oxidizers.

Special Firefighting Procedures: In the event of fire, wear self-contained breathing apparatus. Firefighters should wear full protective clothing. Flammable. Cool fire-exposed containers using water spray.

Section 6 – Accidental Release Measures

Steps To Be Taken If Material Is Released Or Spilled: Evacuate all non-essential personnel. Remove all sources of ignition. Ventilate area. Contain and remove spilled material with inert absorbent and non-sparking tools. Use personal protective equipment as necessary. Dike to prevent entering any sewer or waterway. Soak up with vermiculite or inert absorbent material.

Section 7 - Handling and Storage

Handling: Prevent prolonged breathing of vapors or spray mist. Avoid contact with eyes and skin. Do not take internally. Do not handle until the manufacturers safety precautions have been read and understood. Handle in accordance with good industrial hygiene and safety practice. Keep away from heat and sources of ignition. Use only in ventilated areas. Use safety precautions with empty containers. Empty containers may contain hazardous materials (product residues) in the form of solids, liquids, or vapors. Always use grounding leads when transferring from one container to another. Do not drill, solder, pressurize, grind, cut, weld, or braze empty container. Do not expose empty container to static electricity, heat, flame, sparks, or any source of ignition. Protect container against physical damage.

Storage: Store in buildings designed to comply with OSHA 1910.106. Avoid storing near high temperatures, fire, open flames, and spark sources. Keep containers upright to prevent leakage and tightly closed in a dry, cool, and well-ventilated place. Do not store with oxidizers. Keep container away from incompatible material.

Section 8 - Exposure Controls / Personal Protection

Component ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL
ACETONE 500 ppm 750 ppm 750 ppm 1000 ppm
ISOBUTANE (2-METHYLPROPANE) N.E. N.E. N.E. N.E.
STODDARD SOLVENT (REFINED PETROLEUM DISTILLATE) 100 ppm N.E. 500 ppm N.E.
PROPANE 1000 ppm N.E. 1000 ppm N.E.
METHYL n-PROPYL KETONE 200 ppm 250 ppm 200 ppm 250 ppm
SOLVENT NAPHTHA, LIGHT ALIPHATIC 300 ppm N.E. 300 ppm 400 ppm
AROMATIC HYDROCARBON 100 ppm N.E. N.E. N.E.
PAINT DRIER N.E. N.E. N.E. N.E.
ETHYL BENZENE 100 ppm 125 ppm 100 ppm 125 ppm

 

Notes
ISOBUTANE (2-METHYLPROPANE) CAS# 75-28-5 - Manufacture recommends TLV of 1000 ppm.
METHYL n-PROPYL KETONE CAS# 107-87-9 has been shown to cause harm to the fetus in laboratory animals. It only caused harm at levels of overexposure that would also harm the pregnant animal. The relevance to humans is unknown. It also has been shown to cause mild, reversible kidney effects and mild, reversible liver effects in laboratory animals.
PAINT DRIER CAS# 22464-99-9 - OSHA 29 CFR 1910.1000, Table Z-1 lists Zirconium Compounds (as Zr). ACGIH TWA/TLV 5 mg/m3; TLV/STEL 10 mg/m3
ETHYL BENZENE CAS# 100-41-4 - IARC Group 2B possibly carcinogenic to humans.

 

Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations below permissible OSHA exposure limits. Remove all ignition sources (heat, sparks, flame, and hot surfaces).

Respiratory Protection: A respirator that is recommended or approved for use in an organic vapor environment (air purifying or fresh air supplied) is necessary. Observe OSHA regulations for respirator use. Ventilation should be provided to keep exposure levels below the OSHA permissible limits. A respirator that is recommended or approved for use in an organic vapor environment (air purifying or fresh air supplied) is necessary. Observe OSHA regulations for respirator use. Ventilation should be provided to keep exposure levels below the OSHA permissible limits. If TLV limits can be maintained and documented below the OSHA/ACGIH limits, an air-supplied respirator may not be required. However, other OSHA/NIOSH approved respirators may be used.

Skin Protection: Chemical-resistant gloves (neoprene, natural rubber) should be used to prevent skin contact.

Eye Protection: Wear safety eyewear (safety glasses, safety glasses with side-shields, chemical goggles, or face shields) to prevent eye contact.

Other protective equipment: Long sleeve and long leg clothing is recommended. Remove and wash contaminated clothing before reuse or discard. Safety shower and eyewash station should be located in immediate work area. Wear boots that are chemical-resistant.

Hygienic Practices: Wash hands before breaks, eating, smoking, using washroom, and at the end of the workday.

 Section 9 - Physical and Chemical Properties

 

Boiling Range (°F):

N.D. - 396

Vapor Density:

Heavier than air

Odor:

N.D.

Odor Threshold:

N.D.

Appearance:

Amber liquid in aerosol container

Evaporation Rate:

1.46 x n-Butyl Acetate

Solubility in H2O:

Insoluble

 

 

Freeze Point:

N.D.

Specific Gravity:

0.718

Vapor Pressure:

N.D.

PH:

N.A.

Physical State:

Liquid

Viscosity:

Thin liquid to heavy viscous material

(See section 16 for abbreviation legend)

 Section 10 - Stability and Reactivity

Conditions To Avoid: Avoid high temperatures, sparks, or open flames. Do not breathe vapors or spray mist.

Incompatibility: Material is incompatible with strong oxidizers, reducing agents, strong acids, chromic anhydride, chromyl alcohol, hexachloromelamine, and hydrogen peroxide. In addition, incompatible with permonosulfuric acid, chloroform, alkalis, chlorine compounds, potassium t-butoxide, and thioglycol.

Hazardous Decomposition: Thermal decomposition can lead to the generation and release of gases and vapors including carbon monoxide, carbon dioxide, oxides of nitrogen, and hydrocarbons.

Hazardous Polymerization: Will not occur.

Stability: Stable under recommended storage conditions.

 Section 11 - Toxicological Information

 

Product LD50: N.E.

Product LC50: N.E.

Section 12 - Ecological Information

Ecological Information: No Information.

Section 13 - Disposal Information

Disposal Information: Dispose of waste in accordance with federal, state, and local environmental regulations. Empty containers will contain product residue and flammable vapors. Handle as hazardous material. Do not incinerate closed containers. EPA Hazardous Waste Number/Code: D001, F003, F005. Hazardous Waste Characteristics: Ignitability and Reactivity.

Section 14 - Transportation Information

 

DOT Proper Shipping Name:

Consumer Commodity

Packing Group:

N.A.

DOT Technical Name:

N.A.

Hazard Subclass:

N.A.

DOT Hazard Class:

ORM-D/Aerosol

Resp. Guide Page:

N.A.

DOT UN/NA Number:

N.A.

IATA:

No Information

Section 15 - Regulatory Information

 

CERCLA – SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:  IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD

 

SARA Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Component CAS Number Percent By Weight
PAINT DRIER 22464-99-9 0.20
ETHYL BENZENE 100-41-4 0.15

 

Toxic Substances Control Act:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:

Component CAS Number
METHYL ISOBUTYL KETONE 108-10-1
p-XYLENE OR PARA-XYLENE 106-42-3

 

U.S. State Regulations: As follows –

New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

Component CAS Number
ALKYD RESIN TRADE SECRET

 

 Pennsylvania Right-to-Know:

The following non-hazardous ingredients are present in the product at greater than 3%.

Component CAS Number
ALKYD RESIN TRADE SECRET
URALKYD PROPRIETARY

 

California Proposition 65:

Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Component CAS Number
ETHYL BENZENE 100-41-4
BENZENE 71-43-2
ETHYL BENZENE 100-41-4
NAPTHALENE 91-20-3
BENZENE 71-43-2

 

Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other reproductive hazards.

Component CAS Number
BENZENE 71-43-2
TOLUENE 108-88-3
BENZENE 71-43-2

 

International Regulations: As follows –

CANADIAN WHMIS:  This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.

CANADIAN WHMIS CLASS: N.A.

Section 16 - Other Information

 

HMIS Ratings:

 

 

 

Health: 3

Flammability: 4

Reactivity: 1

Personal Protection: G

 

NFPA Fire Rating: 0

NFPA Health Rating: 0

NFPA Specific Hazard Rating: No Information

NFPA Stability Rating: 0

 

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 553

VOLATILE ORGANIC COMPOUNDS, LB/GAL: 4.61

VOLATILE ORGANIC COMPOUNDS MIXED, GR/LTR: <= N.D.

VOLATILE ORGANIC COMPOUNDS MIXED, LB/GAL: <= N.D.

VOLATILE ORGANIC COMPOUNDS, LB/LB-SOLID: <=

VOLATILE ORGANIC COMPOUNDS OF MATERIAL (SCAQMD RULE 443.1), GR/LTR:  441

VOLATILE ORGANIC COMPOUNDS OF MATERIAL (SCAQMD RULE 443.1), LB/GAL:  3.68

VOLATILE HAPs PER WEIGHT SOLIDS, LB./LB.  0

REASON FOR REVISION:

REGULATORY CODE: 24X01

LAYOUT CODE: A2004R

Legend:  N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information contained on this MSDS has been checked and should be accurate.  However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations.