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Section
1 - Chemical Product / Company Information |
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Product Name: |
INT. POLYURETH. SATIN AEROSOL |
Revision Date: |
04/08/2009 |
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Identification Number: |
24X03 |
Print
Date: |
8-16-2010 |
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Product Use/Class: |
POLYURETHANE |
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Manufacturer: |
Deft,
Inc. (CAGE CODE
33461) |
Information
Phone: Emergency Phone: |
(949)
474-0400 (800) 424-9300 |
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Section
2 - Hazards Identification | |||
*** Emergency Overview ***:
Extremely Flammable! Amber liquid in aerosol container. Harmful by inhalation,
in contact with skin, and if swallowed. Contact with eyes or skin causes
irritation. Affects the central nervous system.
Effects Of Overexposure - Eye
Contact:
Exposure to liquid, aerosol, or vapors may cause irritation, tearing, redness,
and swelling accompanied by a stinging sensation. Direct eye contact may cause
irritation. Damage may occur to the cornea or lens of the eye.
Effects Of Overexposure - Skin
Contact:
Direct skin contact may cause irritation. Symptoms may include swelling,
redness, and rash. Prolonged or repeated skin contact may cause dermatitis,
drying, and defatting due to the solvent properties. It is possible for a
component to pass through the skin into the body, but is unlikely to cause
harmful effects when handled and used safely.
Effects Of Overexposure -
Inhalation:
Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes) & acute nervous system depression characterized by the following
progressive steps: headache, dizziness, staggering gait, confusion,
unconsciousness, or coma. Exposure may cause coughing. Inhalation of vapors may
cause feelings of euphoria and anesthetic effects. Prolonged exposure may cause
narcosis, rapid breathing and death from asphyxiation. Inhalation may cause
headaches, difficult breathing, and loss of consciousness. Respiratory
depression, failure, or death may result from overexposure.
Effects Of Overexposure -
Ingestion: Ingestion may cause
gastrointestinal irritation, abdominal pain, nausea, vomiting, and diarrhea. May
result in possible corrosive action in the mouth, stomach tissue, and digestive
tract. Vomiting may cause aspiration of the solvent, resulting in chemical
pneumonitis. Harmful or fatal if swallowed. Ingestion causes damage to the
central nervous system. It may include, acute nervous system depression, which
is characterized by the following progressive steps: headache, dizziness,
staggering gait, confusion, drowsiness, unconsciousness, or coma. Ingestion may
cause a burning sensation in the mouth and esophagus. Lung inflammation or other
lung injury may occur if methyl n-propyl ketone enters the lungs through
vomiting or swallowing.
Effects Of Overexposure - Chronic
Hazards: Prolonged contact will cause drying and
cracking of the skin, due to defatting action. Skin sensitization, asthma, or
other allergic responses may develop. Listed as a Carcinogen: NTP? : No, IARC
Monographs? : No, OSHA Regulated? : No. Symptoms of overexposure may occur for
up to 48 hours after the original exposure occurred. The neurotoxic effects
caused by other chemicals may be worsened or the time of onset may be shortened
by a component. In addition, kidney and liver damage caused by other chemicals
may be worsened or the time of onset may be shortened by a component. A
component has been shown to cause kidney damage in male rats. The kidney effects
are not expected to effect humans. A component(s) has been shown to cause blood
abnormalities, lower activity of certain immune system cells, effects the
hearing, mild reversible liver effects, central nervous damage, and cataracts in
laboratory animals. Methyl n-propyl ketone, a component of this formulation, has
been shown to cause harm to the fetus in labortory animal studies. Harm to the
fetus occurs only at exposure levels that harm the pregnant animal. The
relevance of these findings to humans is uncertain.
Primary Route(s) Of
Entry: Skin
Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
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Section
3 - Composition / Information On Ingredients |
Component
CAS
Number
Weight % Reporting
Ranges
ACETONE
67-64-1
10-30
ISOBUTANE
(2-METHYLPROPANE)
75-28-5
10-30
STODDARD SOLVENT
(REFINED PETROLEUM DISTILLATE)
8052-41-3
10-30
PROPANE
74-98-6
7-13
METHYL n-PROPYL
KETONE
107-87-9
7-13
SOLVENT NAPHTHA,
LIGHT ALIPHATIC
64742-89-8
1-5
AROMATIC
HYDROCARBON
64742-95-6
1-5
PAINT
DRIER
22464-99-9
0.1-1.0
ALL
INGREDIENTS ARE ON THE TSCA INVENTORY LIST, UNLESS OTHERWISE NOTED IN SECTION
8.
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Section
4 - First Aid Measures |
First Aid - Eye
Contact: If
material gets into eyes, flush with water immediately for 20 minutes. Hold
eyelids open to rinse out the entire eye. Consult a physician. If symptoms
develop (irritation) from airborne exposure, move to fresh air.
First Aid - Skin
Contact:
Remove contaminated clothing and shoes. In case of contact, immediately flush
skin with plenty of water and wash affected areas thoroughly with soap and
water. Wash contaminated clothing thoroughly before reuse or discard. If rash or
other symptoms develop (irritation), consult a physician.
First Aid -
Inhalation:
Move to fresh air in case of accidental inhalation of vapors. Give oxygen or
artificial respiration if needed. Asthmatic type symptoms may develop and maybe
immediate or delayed by several hours. In the case of inhalation of
aerosol/mist, call 911 immediately.
First Aid -
Ingestion: Do
not induce vomiting. Do not give anything to an unconscious person. Obtain
medical help.
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Section
5 - Fire Fighting Measures |
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Flash Point (°F): < 20 TCC |
LOWER EXPLOSIVE LIMIT (%): 0.9 |
UPPER EXPLOSIVE LIMIT (%): 12. |
Extinguishing Media: Alcohol Foam, Carbon Dioxide, Dry Chemical, Foam, Water Fog, Water Spray, Dry Sand
Unusual Fire And Explosion Hazards: Keep containers tightly closed. Isolate from heat, sparks, electrical equipment and open flame. Fire or intense heat may cause violent rupture of packages. Application to hot surfaces requires special precautions. Toxic gases may form when product burns. Remove all sources of ignition. Vapors and fumes may form an ignitable/explosive mixture with air. Vapors are heavier than air and may flow along surfaces, may travel/spread along the floors/ground, or can be moved by ventilation to a distant ignition source and flashback. Do not use a cutting or welding torch near or on a drum of product, because vapors may ignite explosively, even if the drum is empty and contains only product residue. Fire may ensue when product comes in contact with strong oxidizers.
Special Firefighting Procedures: In the event of fire, wear self-contained breathing apparatus. Firefighters should wear full protective clothing. Flammable. Cool fire-exposed containers using water spray.
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Section
6 – Accidental Release Measures |
Steps To Be Taken If Material Is
Released Or Spilled: Evacuate all non-essential personnel. Remove all sources of
ignition. Ventilate area. Contain and remove spilled material with inert
absorbent and non-sparking tools. Use personal protective equipment as
necessary. Dike to prevent entering any sewer or waterway. Soak up with
vermiculite or inert absorbent material.
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Section
7 - Handling and Storage |
Handling: Prevent prolonged
breathing of vapors or spray mist. Avoid contact with eyes and skin. Do not take
internally. Do not handle until the manufacturers safety precautions have been
read and understood. Handle in accordance with good industrial hygiene and
safety practice. Keep away from heat and sources of ignition. Use only in
ventilated areas. Use safety precautions with empty containers. Empty containers
may contain hazardous materials (product residues) in the form of solids,
liquids, or vapors. Always use grounding leads when transferring from one
container to another. Do not drill, solder, pressurize, grind, cut, weld, or
braze empty container. Do not expose empty container to static electricity,
heat, flame, sparks, or any source of ignition. Protect container against
physical damage.
Storage: Store in buildings designed
to comply with OSHA 1910.106. Avoid storing near high temperatures, fire, open
flames, and spark sources. Keep containers upright to prevent leakage and
tightly closed in a dry, cool, and well-ventilated place. Do not store with
oxidizers.
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Section
8 - Exposure Controls / Personal Protection |
Component
ACGIH
TLV
ACGIH
STEL
OSHA
PEL
OSHA
STEL
ACETONE
500
ppm
750
ppm
750
ppm
1000
ppm
ISOBUTANE
(2-METHYLPROPANE)
N.E.
N.E.
N.E.
N.E.
STODDARD SOLVENT
(REFINED PETROLEUM DISTILLATE)
100
ppm
N.E.
500
ppm
N.E.
PROPANE
1000
ppm
N.E.
1000
ppm
N.E.
METHYL n-PROPYL
KETONE
200
ppm
250
ppm
200
ppm
250
ppm
SOLVENT NAPHTHA,
LIGHT ALIPHATIC
300
ppm
N.E.
300
ppm
400
ppm
AROMATIC
HYDROCARBON
100
ppm
N.E.
N.E.
N.E.
PAINT
DRIER
N.E.
N.E.
N.E.
N.E.
Notes
ISOBUTANE
(2-METHYLPROPANE) CAS# 75-28-5 - Manufacture recommends TLV of 1000
ppm.
METHYL n-PROPYL
KETONE CAS# 107-87-9 has been shown to cause harm to the fetus in
laboratory animals. It only caused harm at levels of overexposure that
would also harm the pregnant animal. The relevance to humans is unknown.
It also has been shown to cause mild, reversible kidney effects and mild,
reversible liver effects in laboratory
animals.
PAINT DRIER CAS#
22464-99-9 - OSHA 29 CFR 1910.1000, Table Z-1 lists Zirconium Compounds
(as Zr). ACGIH TWA/TLV 5 mg/m3; TLV/STEL 10
mg/m3
Engineering Controls: Local
ventilation of emission sources may be necessary to maintain ambient
concentrations below permissible OSHA exposure limits. Remove all ignition
sources (heat, sparks, flame, and hot surfaces).
Respiratory Protection: A respirator
that is recommended or approved for use in an organic vapor environment (air
purifying or fresh air supplied) is necessary. Observe OSHA regulations for
respirator use. Ventilation should be provided to keep exposure levels below the
OSHA permissible limits. A respirator that is recommended or approved for use in
an organic vapor environment (air purifying or fresh air supplied) is necessary.
Observe OSHA regulations for respirator use. Ventilation should be provided to
keep exposure levels below the OSHA permissible limits. If TLV limits can be
maintained and documented below the OSHA/ACGIH limits, an air-supplied
respirator may not be required. However, other OSHA/NIOSH approved respirators
may be used.
Skin Protection: Chemical-resistant
gloves (neoprene, natural rubber) should be used to prevent skin
contact.
Eye Protection: Wear safety eyewear
(safety glasses, safety glasses with side-shields, chemical goggles, or face
shields) to prevent eye contact.
Other protective equipment: Long
sleeve and long leg clothing is recommended. Remove and wash contaminated
clothing before reuse or discard. Wear boots that are
chemical-resistant.
Hygienic Practices: Wash hands
before breaks, eating, smoking, using washroom, and at the end of the
workday.
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Section 9 - Physical
and Chemical Properties |
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Boiling Range (°F): |
N.D. - 396 |
Vapor Density: |
Heavier than air |
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Odor: |
N.D. |
Odor Threshold: |
N.D. |
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Appearance: |
Amber liquid in aerosol container |
Evaporation Rate: |
1.46 x n-Butyl Acetate |
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Solubility in H2O: |
Insoluble |
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Freeze Point: |
N.D. |
Specific Gravity: |
0.725 |
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Vapor Pressure: |
N.D. |
PH: |
N.A. |
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Physical State: |
Liquid |
Viscosity: |
Thin liquid to heavy viscous material |
(See section 16 for abbreviation
legend)
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Section 10 - Stability
and Reactivity |
Conditions To Avoid: Avoid high temperatures, sparks, or open flames. Do not breathe vapors or spray mist.
Incompatibility: Material is
incompatible with strong oxidizers, reducing agents, strong acids, chromic
anhydride, chromyl alcohol, hexachloromelamine, and hydrogen peroxide. In
addition, incompatible with permonosulfuric acid, chloroform, alkalis, chlorine
compounds, potassium t-butoxide, and thioglycol.
Hazardous Decomposition: Thermal
decomposition can lead to the generation and release of gases and vapors
including carbon monoxide, carbon dioxide, oxides of nitrogen, and
hydrocarbons.
Hazardous Polymerization: Will not
occur.
Stability: Stable under recommended
storage conditions.
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Section 11 -
Toxicological Information |
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Product LD50: N.E. |
Product LC50: N.E. |
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Section 12 -
Ecological Information | |
Ecological Information: No
Information.
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Section 13 - Disposal
Information |
Disposal Information: Dispose of
waste in accordance with federal, state, and local environmental regulations.
Empty containers will contain product residue and flammable vapors. Handle as
hazardous material. Do not incinerate closed containers. EPA Hazardous Waste
Number/Code: D001, F003, F005. Hazardous Waste Characteristics: Ignitability and
Reactivity.
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Section 14 -
Transportation Information |
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DOT Proper Shipping Name: |
Consumer Commodity |
Packing Group: |
N.A. |
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DOT Technical Name: |
N.A. |
Hazard Subclass: |
N.A. |
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DOT Hazard Class: |
ORM-D/Aerosol |
Resp. Guide Page: |
N.A. |
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DOT UN/NA Number: |
N.A. |
IATA: |
No Information |
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Section 15 -
Regulatory Information | |||
CERCLA – SARA Hazard
Category
This product has been reviewed
according to the EPA ‘Hazard Categories’ promulgated under Sections 311and 312
of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and
is considered, under applicable definitions, to meet the following
categories: IMMEDIATE HEALTH
HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA Section 313:
This product contains the following
substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part
372:
Component
CAS
Number
Percent By
Weight
PAINT
DRIER
22464-99-9
0.14
Toxic Substances Control
Act:
This product contains the following
chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
Component
CAS
Number
METHYL ISOBUTYL
KETONE
108-10-1
p-XYLENE OR
PARA-XYLENE
106-42-3
U.S. State Regulations: As follows
–
New Jersey
Right-to-Know:
The following materials are
non-hazardous, but are among the top five components in this product.
Component
CAS
Number
ALKYD
RESIN
TRADE
SECRET
Pennsylvania
Right-to-Know:
The following non-hazardous
ingredients are present in the product at greater than 3%.
Component
CAS
Number
ALKYD
RESIN
TRADE
SECRET
California Proposition
65:
Warning: The following ingredients
present in the product are known to the state of California to cause
Cancer:
Component
CAS
Number
ETHYL
BENZENE
100-41-4
SILICA, CRYSTALLINE
(QUARTZ)
14808-60-7
BENZENE
71-43-2
ETHYL
BENZENE
100-41-4
NAPTHALENE
91-20-3
BENZENE
71-43-2
Warning: The following ingredients
present in the product are known to the state of California to cause birth
defects, or other reproductive hazards.
Component
CAS
Number
BENZENE
71-43-2
TOLUENE
108-88-3
BENZENE
71-43-2
International Regulations: As
follows –
CANADIAN WHMIS: This MSDS has been prepared in
compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS
CLASS:
N.A.
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Section 16 - Other
Information |
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HMIS Ratings: |
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Health: 3 |
Flammability: 4 |
Reactivity: 1 |
Personal Protection: G |
NFPA Fire Rating: 0
NFPA Health Rating: 0
NFPA Specific Hazard Rating:
No
Information
NFPA Stability Rating:
0
VOLATILE ORGANIC COMPOUNDS, GR/LTR:
541
VOLATILE ORGANIC COMPOUNDS, LB/GAL:
4.52
VOLATILE ORGANIC COMPOUNDS MIXED,
GR/LTR: <= N.D.
VOLATILE ORGANIC COMPOUNDS MIXED,
LB/GAL: <= N.D.
VOLATILE ORGANIC COMPOUNDS,
LB/LB-SOLID: <=
VOLATILE ORGANIC COMPOUNDS OF
MATERIAL (SCAQMD RULE 443.1), GR/LTR: 431
VOLATILE ORGANIC COMPOUNDS OF
MATERIAL (SCAQMD RULE 443.1), LB/GAL: 3.59
VOLATILE HAPs PER WEIGHT SOLIDS,
LB./LB. 0
REASON FOR REVISION:
REGULATORY CODE: 24X03
LAYOUT CODE: A2004R
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of the user to comply with all Federal, State, and Local laws and regulations.